No you cant. However if you have not yet taken your VISA interview, then you can change it before the interview. But once you have got VISA, you cant change it. You have to apply for a new VISA all over again. Hope this helps.
Perhaps you can apply for a visitor's Visa (for tourism) and later get the student's Visa. That way you can at least enter the US and attend your program. I'm not sure however how/if it works.
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