For the maximum utilization, let blue cubes are put on the surface ...
Say, 8 corners of the larger cube are the blue cubes (i.e., 3 smaller surfaces are utilized) and the rest of the 2 are on the edges (i.e., 2 smaller surfaces are utilized)
8*3 + 2*2 = 28 smaller blue surfaces
totally there are 6*9 = 54 smaller surfaces ...
Hence the largest fraction part of the surface area of the large cube that could be blue = 28/54 = 14/27



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