In general, your econometric specification should be driven by your economic model. In other words, the regression you run should be derived from your optimization problem (it's often a first order condition or transformation of a first order condition).
There are a lot of ways to test for model fit, depending on what your options are. A "minimum chi squared" test is one good alternative for testing linear vs. higher power models. Do NOT simply rely on the r-squared of the regression to tell you which model fits better. Model selection is one of the fundamental parts of econometric analysis, and it's not something you want to rely on your software to do for you. It should be based on the economic principles of the question, and tested to the extent possible.



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